Atom Probe Tomography.

Local Electrode Atom Probe LEAP

Local Electrode Atom Probe - LEAP

The LEAP series is CAMECA's cutting edge atom probe microscope.

Key Features.

 
  • Optimized detection efficiency provides unparalleled sensitivity

  • Large Field-of-View and detection uniformity - the ultimate 3D spatial resolution

  • Sub-nanometer 3D

  • Isotopic/Elemental information

  • Time-of-flight mass spectrometry (ToF)

  • Equal sensitivity to all elements across the periodic table, even H.

  • Spatial resolution, x,y 0.3–0.5 nm, z (depth) <0.2 nm

  • Mass resolution dm/m < 1/1000 FWHM

  • Sensitivity < 5 atomic ppm (0.000005 at.%)

 Application Examples

Metals & Alloys

The properties of metallic engineering materials are defined by their microstructure, grain boundaries, precipitates and interfaces. APT offers unparalleled insight from the micro-to-atomic scale in materials such as:

  • Steel

  • Aluminum alloys

  • Super alloys (Fe, Ni, Co-based)

  • High-entropy alloys

  • Titanium alloys

  • Magnesium alloys

 

Nickel-based superalloy.

 

Semi Conductors

APT is widely used in industry and science to explore atomic structure and interfaces in different semiconductor devices, such as:

  • Light Emitting Diodes (LEDs),

  • Solar Cells and Transparent Conductive Oxides (TCOs),

  • Field-Effect Transistors (FETs),

  • Metal-Oxide-Semiconductor Field-Effect Transistors (MOSFETs)

  • Static or Dynamic Random Access Memory (SRAM or DRAM)

 

Aluminum Doped Zinc-Oxide (AZO)

 

Geology Materials

APT is increasing developed and used in the geoscience and planetary science disciplines in recent years.

It has the ability to provide sub-nanometre resolution of whole periodic elements and isotopic compositions, without spending much time for a prior selection. That’s why APT can help determing the bulk composition of natural mineral and metallic grains that are too small to be quantitatively analysed by other techniques.

 

Baddeleyite (ZrO2)

(Steven M. Reddy - Atom Probe Tomography Development and Application to the Geosciences)

 

Battery Materials

The high-capacity energy storage needed in electric vehicles or grid energy storage is currently largely achieved using Li-ion batteries.

It is important to understand the factors determing battery capacity and their degradation mechanisms, in order to ensure long-term, sustainable and safe operation. This requires detailed knowledge of their microstructure and chemistry, and their evolution under operating conditions, on the nanoscale.

APT provides 3D compositional mapping with sub-nanometre resolution. It is very sensitive and not related to the atomic weight, hence Li can be readily detected. APT result can demonstrate and explain irreversible capacity loss of battery.

 

Nanoparticle powder Li4Ti5O12 (LTO). Scale bar is 20 nm.

(Se-Ho Kim - Atom probe analysis of electrode materials for Li-ion batteries: challenges and ways forward)

 

Ceramics

Engineering ceramics, such as oxides, nitrides, and carbides, are group of important material used in electronic devices, aerospace components, as well as various tribological applications. APT provides analysis and mapping for individual atoms in three dimensions of interfaces in these materials. Therefore engineers can fully understand their features such as electronic, ionic, mechanical, magnetic, and optical properties, and hence develop the technologies to limit the thermal growth of oxides to improve energy efficiency.

In the past, this atomic-scale characterization technique required the material to have high electrical conductivity. With the development of the focused ion beam milling technique for specimen preparation, and commercial APT instruments, it is feasible for three-dimensional analysis with nearly atomic resolution of insulating oxide and nitride ceramics, semiconductors, and even biological materials.

 

Nanocomposite ceramics made of 3 mol.% Y2O3 stabilized tetragonal ZrO2 with 30 vol.% MgAl2O4 spinel.

(Y.M. Chen - Laser-assisted atom probe analysis of zirconia/spinel nanocomposite ceramics)

 

Bio Minerals

Biomineralization is the process by which living organisms produce minerals, often to harden existing tissues. Biominerals are composites of mineral and organic phases. Biominerals are used in conjunction with organic polymers such as collagen and chitin to give structural support to bones and shells.

The characterization of the distribution of such nanoscale structure is very challenging. Even energy-filtered electron microscopy is not suitable for study of small quantities of low atomic number elements typical for biological materials. Therefore, APT can be used for this purpose with the advanced ability of obtaining quantitative chemical data.

 
 

3D reconstruction of a sample of elephant tusk dentin.

(Lyle M. Gordon - Atom Probe Tomography of Apatites and Bone-Type Mineralized Tissues)

Science. That’s Nova.